Эта публикация цитируется в
2 статьях
Communications
Reactions of cyrene with formaldehyde
Yu. A. Khalilova,
L. Kh. Faizullina,
Sh. M. Salikhov,
F. A. Valeev Ufa Institute of Chemistry, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
Аннотация:
Cyrene reacts with 35% aqueous formaldehyde in the presence of K
2CO
3, tetramethylguanidine and Et
3N to give three products,
viz., major α,α-bis(hydroxymethyl) derivative, a product of its keto group reduction, and 3,5,11,12-tetraoxatricyclo[7.2.1.0
2,7]dodecan-2-ol. The options for the derivatization of the hydroxy groups with benzyl, tosyl, isopropylidene, and methylene acetal protecting groups were studied.
Ключевые слова:
cyrene, levoglucosenone, formaldehyde, enolization, chiral dioxane, diol.
Язык публикации: английский
DOI:
10.1016/j.mencom.2023.09.019
Полный текст:
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