A. E. Gekhman, N. I. Moiseeva, V. V. Minin, G. M. Larin, I. I. Moiseev, “Interaction between singlet dioxygen and superoxide anion radical coordinated with vanadium(V) ion”, Mendeleev Commun., 7:6 (1997), 221

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Interaction between singlet dioxygen and superoxide anion radical coordinated with vanadium(V) ion

A. E. Gekhman, N. I. Moiseeva, V. V. Minin, G. M. Larin, I. I. Moiseev

N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: Abnormal broadening of the V^V(O₂·⁻) EPR signal in the V^V/H₂O₂/AcOH system known to generate singlet dioxygen has been observed; this effect suggests that ¹O₂ serves as an effective relaxing agent, broadening the V^V(O₂·⁻) EPR signal.

Язык публикации: английский

DOI: 10.1070/MC1997v007n06ABEH000840