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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 1995, том 5, выпуск 2, страницы 62–63 (Mi mendc5032)

Эта публикация цитируется в 3 статьях

Clathrate Hydrates in the Water–Tetrahydropyran System at High Pressure

Yu. A. Dyadin, T. V. Mikina, F. V. Zhurko, Yu. I. Mironov, A. V. Manuilov, G. Skripko

A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Аннотация: Tetrahydropyran (THP) forms a clathrate hydrate THP·17H2O of cubic structure II which melts at P = 1 atm, T= – 0.8°C decomposing into two liquids with an upper consolute temperature of dissolution of 226 °C. It is destabilized by pressure and at P > 1.15 kbar, T= – 4.3°C cubic structure I hydrate appears to become stable.

Язык публикации: английский

DOI: 10.1070/MC1995v005n02ABEH000458



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