R. M. Gainullin, A. V. Il'yasov, K. M. Salikhov, “A 31P CIDNP Study of the Reactions of Dithiophosphate Metal Complexes at Various Magnetic Fields”, Mendeleev Commun., 5:3 (1995), 113

A ³¹P CIDNP Study of the Reactions of Dithiophosphate Metal Complexes at Various Magnetic Fields

R. M. Gainullin^a, A. V. Il'yasov^a, K. M. Salikhov^b

^a A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
^b E.K. Zavoiskii Kazan' Physicotechnical Institute, Kazan Scientific Centre of the Russian Academy of Sciences, Russian Federation

Аннотация: The reactions of dithiophosphate metal complexes of zinc(II), nickel(II), copper(VI) and molybdenum(vi) with cumene and tert-butyl hydroperoxides have been investigated by ³¹P CIDNP and the reaction rate constants determined; information about the spin dynamics of the radical pair has been obtained.

Язык публикации: английский

DOI: 10.1070/MC1995v005n03ABEH000483