H. J. Frohn, V. V. Bardin, “Unexpected Reactions of (Heptafluoro-1,4-cyclohexadien-1-yl)xenon(II) Hexafluoroarsenate with Sodium Fluoride and Antimony Pentafluoride”, Mendeleev Commun., 5:3 (1995), 114

Эта публикация цитируется в 7 статьях

Unexpected Reactions of (Heptafluoro-1,4-cyclohexadien-1-yl)xenon(II) Hexafluoroarsenate with Sodium Fluoride and Antimony Pentafluoride

H. J. Frohn^a, V. V. Bardin^b

^a Fachgebiet Anorganische Chemie, Gerhard-Mercator-Universitat, Duisburg, Germany
^b N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Аннотация: The reactivity of (heptafluoro-1,4-cyclohexadien-1-yl)xenon(ii) hexafluoroarsenate 1 towards a fluoride donor and acceptor has been investigated; the interaction of 1 with NaF led to perfluoro-3-methylenecyclopentene and xenon. No dication [C₆F₆Xe]²⁺ was detected by ¹⁹F NMR spectroscopy when [1-Xe ⁺ -1,4-C₆F₇] [AsF₆]^– was treated with SbF₅–SO₂, SbF₅–SO₂FCI or neat SbF₅.

Язык публикации: английский

DOI: 10.1070/MC1995v005n03ABEH000484