V. A. Benderskii, A. U. Goldschleger, A. V. Akimov, E. Ya. Misochko, Ch. A. Wight, “Low Temperature Free Radical Addition Reactions in Solid Argon: F + C2H4, an EPR Study”, Mendeleev Commun., 5:6 (1995), 245

Эта публикация цитируется в 3 статьях

Low Temperature Free Radical Addition Reactions in Solid Argon: F + C₂H₄, an EPR Study

V. A. Benderskii^a, A. U. Goldschleger^a, A. V. Akimov^a, E. Ya. Misochko^a, Ch. A. Wight^b

^a Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^b Department of Chemistry, University of Utah, Salt Lake City, Utah, USA

Аннотация: Ultraviolet laser photolysis of dilute mixtures of F₂ and C₂H₄ in solid argon form a 2-fluoroethyl radical by addition of translationally ‘hot’ as well as thermal F atoms to ethene; at T > 20 K the major channel is the thermal reaction, which converts up to 25% of ethene to 2-fluoroethyl radical.

Язык публикации: английский

DOI: 10.1070/MC1995v005n06ABEH000549