Unexpected Transformations of 4-Azido-2-(2’-hydroxyphenyl)-5-ethoxycarbonyl-pyrimidine: the Formation of 4-Hydroxyamino-2-(2’-hydroxyphenyl)- 5-ethoxycarbonylpyrimidine and Ethyl 3-(2’-Hydroxybenzoylamino)- 2-(1” H-tetrazol-5” -yl)acrylate
Аннотация:
The title compound undergoes a spontaneous solid-phase transformation in the dark into 3 and 4 at room temperature. On refluxing azide 2A in water, the hydroxylamine 4 was afforded in good yield.