M. N. Vargaftik, Yu. T. Struchkov, A. I. Yanovsky, P. M. Maitlis, “Synthesis and X-Ray Structure of Cp*Rh(III)-Molybdate Complexes Derived from Bis(triphenylphosphineiminium) Mono- and Polymolybdates”, Mendeleev Commun., 3:6 (1993), 247

Эта публикация цитируется в 8 статьях

Synthesis and X-Ray Structure of Cp^*Rh(III)-Molybdate Complexes Derived from Bis(triphenylphosphineiminium) Mono- and Polymolybdates

M. N. Vargaftik^a, Yu. T. Struchkov^b, A. I. Yanovsky^b, P. M. Maitlis^c

^a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^c Department of Chemistry, University of Sheffield, Sheffield, UK

Аннотация: Reaction of [{Cp^*RhCI₂}₂] (Cp^*=η⁵-C₅Me₅) with the PPN (PPN⁺ = Ph₃P=N=PPh₃⁺) salts of iso- and heteropolymolybdates offers a good route to polyoxometallates containing organometallics; the syntheses and X-ray structures of [(Cp^*Rh)₄(Mo₄O₁₆)], containing a tris-cubane oxotetramolybdenum skeleton (derived from (PPN)₂[MoO₄]-6H₂O) and the ionic [Cp^*RhCl₃RhCp^*]⁺[PPN]⁺₂[PMo₁₂O₄₀]³⁻ (derived from (PPN)₂[Mo₂O₇]) are described.

Язык публикации: английский

DOI: 10.1070/MC1993v003n06ABEH000314