V. S. Belova, A. M. Khenkin, V. N. Postnov, V. E. Prusakov, A. E. Shilov, M. L. Stepanova, “Oxidation of Alkanes by Dioxygen in the Presence of an Iron Complex immobilized on Modified Silica. Chemical Model of Methane Monooxygenase”, Mendeleev Commun., 2:1 (1992), 7

Эта публикация цитируется в 10 статьях

Oxidation of Alkanes by Dioxygen in the Presence of an Iron Complex immobilized on Modified Silica. Chemical Model of Methane Monooxygenase

V. S. Belova^a, A. M. Khenkin^a, V. N. Postnov^b, V. E. Prusakov^a, A. E. Shilov^c, M. L. Stepanova^a

^a Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^b St. Petersburg State University, St. Petersburg, Russian Federation
^c N.M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: A model is proposed for the activation of O₂ by methane monooxygenase using a supported binuclear iron complex as a catalytic centre in the presence of Zn as a reducing agent, methylviologen as a mediator, and acetic acid as an effector.

Язык публикации: английский

DOI: 10.1070/MC1992v002n01ABEH000095