V. N. Khabashesku, V. Balaji, S. E. Boganov, S. A. Bashkirova, P. M. Matveichev, E. A. Chernyshev, O. M. Nefedov, J. Michl, “Matrix Isolation and Photochemical Interconversion of Siiacyciopentadienes”, Mendeleev Commun., 2:1 (1992), 38

Эта публикация цитируется в 14 статьях

Matrix Isolation and Photochemical Interconversion of Siiacyciopentadienes

V. N. Khabashesku^a, V. Balaji^a, S. E. Boganov^b, S. A. Bashkirova^c, P. M. Matveichev^c, E. A. Chernyshev^c, O. M. Nefedov^b, J. Michl^a

^a Department of Chemistry and Biochemistry, University of Colorado at Boulder, Boulder, USA
^b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^c State Scientific Research Institute of Chemistry and Technology of Organoelement Compounds, Moscow, Russian Federation

Аннотация: 1-Silacyclopenta-2,4-diene 1 has been generated by vacuum pyrolysis of 5-silaspiro[4.4]nona-2,7-diene 5 and by photolysis of matrix-isolated 1,1-diazido-1-silacyclopent-3-ene 6, and characterized by matrix-isolation IR and UV spectroscopy; reversible interconversion of 1 with 1-silacyclopenta-1,3-diene 2, 1-silacyclopenta-1,4-diene 3 and 1-silacyclopent-3-ene-1,1-diyl 4 has been observed upon irradiation at various wavelengths; the red-shifted UV absorption of 2 and 3, together with their low Si=C stretching frequencies, provide evidence for Si=C—C=C π conjugation.

Язык публикации: английский

DOI: 10.1070/MC1992v002n01ABEH000118