A. B. Sorokin, A. M. Khenkin, A. E. Shilov, “Base Acceleration of Alkane Oxidation by an Iron-porphyrin−Hypochlorite System. Activity, Selectivity and Kinetic Isotope Effect”, Mendeleev Commun., 2:4 (1992), 137

Эта публикация цитируется в 6 статьях

Base Acceleration of Alkane Oxidation by an Iron-porphyrin−Hypochlorite System. Activity, Selectivity and Kinetic Isotope Effect

A. B. Sorokin^a, A. M. Khenkin^a, A. E. Shilov^b

^a Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^b N.M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: Addition of alkali strongly accelerates the oxidation of cyciohexane by an iron tetramesitylporphyrin−NaOCl system, the selectivity of the reaction and the H−D kinetic isotope effect also being affected; possible mechanisms of OH⁻ action are discussed

Язык публикации: английский

DOI: 10.1070/MC1992v002n04ABEH000172