K. E. Shepelenko, K. A. Nikolaeva, M. A. Shevchenko, Yu. N. Tkachenko, M. E. Minyaev, V. M. Chernyshev, “Ruthenium complexes with chelating carboxylate-NHC ligands as efficient catalysts for C–H arylation in water”, Mendeleev Commun., 32:2 (2022), 205

Эта публикация цитируется в 11 статьях

Communications

Ruthenium complexes with chelating carboxylate-NHC ligands as efficient catalysts for C–H arylation in water

K. E. Shepelenko^a, K. A. Nikolaeva^a, M. A. Shevchenko^a, Yu. N. Tkachenko^a, M. E. Minyaev^b, V. M. Chernyshev^a

^a Platov South-Russian State Polytechnic University, Novocherkassk, Russian Federation
^b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: Ruthenium(ii) complexes with chelating N-heterocyclic carbene (NHC) ligands were studied in the arylation of phenyl group in 2-phenylpyridine and 1-phenylpyrazole with aryl chlorides in water. Complexes with NHC-ligands containing a hemilabile coordinating N-carboxylatomethyl group enable fast and selective ortho-CH-diarylation in the absence of carboxylate-assisting additives.

Ключевые слова: ruthenium complexes, CH-activation, arylation, N-heterocyclic carbene ligands, carboxylate assistance.

Язык публикации: английский

DOI: 10.1016/j.mencom.2022.03.017

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