E. S. Vlasenko, I. A. Nikovsky, Yu. V. Nelyubina, A. A. Korlyukov, V. V. Novikov, “Metal–organic framework ZIF-8 loaded with rhodium nanoparticles as a catalyst for hydroformylation”, Mendeleev Commun., 32:3 (2022), 320

Эта публикация цитируется в 10 статьях

Communications

Metal–organic framework ZIF-8 loaded with rhodium nanoparticles as a catalyst for hydroformylation

E. S. Vlasenko^ab, I. A. Nikovsky^a, Yu. V. Nelyubina^a, A. A. Korlyukov^a, V. V. Novikov^ab

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b National Research University Higher School of Economics (HSE University), Moscow, Russian Federation

Аннотация: Porous metal–organic framework ZIF-8 materials containing incorporated rhodium (Rh@ZIF-8) and rhodium chloride (RhCl₃@ZIF-8) nanoparticles were obtained and tested as a catalytic reaction vessel in the reactions of hydroformylation of 1-decene and styrene. Catalytic tests with Rh@ZIF-8 showed that the selectivity and conversion of the hydroformylation reaction depended on the size of the substrate molecule. The incorporation of catalytic nanoparticles into the pores of a metal–organic framework opens up new possibilities for regioselective hydroformylation.

Ключевые слова: hydroformylation, metal–organic frameworks, reaction vessel, catalyst, rhodium nanoparticles, regioselectivity.

Язык публикации: английский

DOI: 10.1016/j.mencom.2022.05.009

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