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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2022, том 32, выпуск 3, страницы 395–396 (Mi mendc676)

Эта публикация цитируется в 5 статьях

Communications

One-pot assembling of selenazolines from elemental selenium, alkenes and acetonitrile

E. O. Kurkutov, B. A. Shainyan

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation


Аннотация: A new method for assembling 1,3-selenazolines by the iodine- mediated reaction of the simplest building blocks such as elemental selenium, alkenes and acetonitrile has been discovered. A proposed mechanism includes the addition of the intermediate selenium iodides to alkene with subsequent solvent interception by the formed seleniranium ion.

Ключевые слова: selenium, organoselenium compounds, alkenes, acetonitrile, iodine assistance, solvent interception, 1,3-selenazolines.

Язык публикации: английский

DOI: 10.1016/j.mencom.2022.05.035



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