A. A. Komarova, D. V. Muratov, D. S. Perekalin, “Cyclopentadienyl rhodium(III) complexes as catalysts for the insertion of phenyldiazoacetate into E−H bonds”, Mendeleev Commun., 32:4 (2022), 482

Communications

Cyclopentadienyl rhodium(III) complexes as catalysts for the insertion of phenyldiazoacetate into E−H bonds

A. A. Komarova^a, D. V. Muratov^a, D. S. Perekalin^ab

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b G.V. Plekhanov Russian University of Economics, Moscow, Russian Federation

Аннотация: Rhodium(III) complexes catalyze the insertion of carbenoids generated from diazo compounds into E−H bonds (E = B, Si, N, but not C), although less efficiently than classical rhodium(II) carboxylates, despite formally higher oxidation state of the metal.

Ключевые слова: rhodium complexes, diazo compounds, insertion, catalysis, cyclopentadienyl ligands.

Язык публикации: английский

DOI: 10.1016/j.mencom.2022.07.017

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