Ya. V. Demyanov, M. I. Rakhmanova, I. Yu. Bagryanskaya, A. V. Artem'ev, “1D CuI coordination polymers based on triphenylarsine and N,N'-ditopic co-ligands: synthesis, crystal structure and TADF properties”, Mendeleev Commun., 32:5 (2022), 649

Эта публикация цитируется в 8 статьях

Communications

1D Cu^I coordination polymers based on triphenylarsine and N,N'-ditopic co-ligands: synthesis, crystal structure and TADF properties

Ya. V. Demyanov^a, M. I. Rakhmanova^a, I. Yu. Bagryanskaya^b, A. V. Artem'ev^a

^a A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^b N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Аннотация: 1D coordination polymers [Cu₂I₂(AsPh₃)₂(L)]_n (L = 4,4'-bi-pyridine, pyrazine) were synthesized via the reaction of CuI with AsPh₃ and N,N'-ditopic co-ligand s L. At ambient temperature, these polymers exhibit short-lived (2.3–3.2 μs) thermally activated delayed fluorescence (TADF) with _max at 530 nm (L = 4,4'-bipyridine) and 605 nm (L = pyrazine) and quantum efficiency up to 45%.

Ключевые слова: copper(I) iodide, triphenylarsine, coordination polymers, photoluminescence, thermally activated delayed fluorescence.

Язык публикации: английский

DOI: 10.1016/j.mencom.2022.09.027

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