K. S. Andriasov, K. N. Sedenkova, M. G. Eremenko, I. P. Gloriozov, Yu. K. Grishin, T. S. Kuznetsova, E. B. Averina, “Direct oxidative functionalization of saturated dispiro-cyclopropanated bicyclo[3.3.1]nonanes”, Mendeleev Commun., 31:3 (2021), 294

Communications

Direct oxidative functionalization of saturated dispiro-cyclopropanated bicyclo[3.3.1]nonanes

K. S. Andriasov^a, K. N. Sedenkova^ab, M. G. Eremenko^a, I. P. Gloriozov^a, Yu. K. Grishin^a, T. S. Kuznetsova^a, E. B. Averina^ab

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b Institute of Physiologically Active Compounds, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation

Аннотация: Two dispiro[cyclopropane-1,3’-bicyclo[3.3.1]nonane-7′,1″-cyclopropanes] were treated with various oxidative systems. The conditions providing mono- or dioxidation of the CH₂ groups neighbouring to spiro-annulated cyclopropane moieties to afford the corresponding mono- or diketones were found.

Ключевые слова: cyclopropanes, bicyclo[3.3.1]nonanes, cyclopropyl ketones, spiro compounds, 1,5-diketones, oxidation, ozone, ruthenium(VIII) oxide, methyl(trifluoromethyl)dioxirane.

Язык публикации: английский

DOI: 10.1016/j.mencom.2021.04.005

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