L. Wang, N. Zhang, “One-pot synthesis of 5-phenylsulfonyl-3-aroylisoxazolines and 3-aroylisoxazoles from alkynes and (phenylsulfonyl)ethene”, Mendeleev Commun., 31:3 (2021), 390

Эта публикация цитируется в 2 статьях

Communications

One-pot synthesis of 5-phenylsulfonyl-3-aroylisoxazolines and 3-aroylisoxazoles from alkynes and (phenylsulfonyl)ethene

L. Wang^a, N. Zhang^b

^a School of Chemical and Pharmaceutical Engineering, Changzhou Vocational Institute of Engineering, Changzhou, P.R. China
^b Division of General Studies, Changzhou Vocational Institute of Engineering, Changzhou, P.R. China

Аннотация: Iron(III) nitrate-assisted cycloaddition of (phenylsulfonyl)ethene to arylacetylenes in the presence of KI affords 5-phenylsulfonyl-3-aroylisoxazolines whose treatment with K₂CO₃ provides 4,5-unsubstituted 3-aroylisoxazoles. Both synthetic steps can be performed in a one-pot manner.

Ключевые слова: iron nitrate, nitration, alkynes, 1,3-dipolar cycloaddition, isoxazolines, isoxazoles.

Язык публикации: английский

DOI: 10.1016/j.mencom.2021.04.036

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