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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2021, том 31, выпуск 3, страницы 397–399 (Mi mendc942)

Эта публикация цитируется в 3 статьях

Communications

Second generation phenylene dendrimer, 1,3,5-tris[4-(3,5-diphenylphenyl)phenyl]benzene, as a precursor of a new carbon material

I. A. Khotina, N. S. Kushakova, V. G. Kharitonova, D. V. Kupriyanova, S. A. Babich, A. I. Kovalev

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation


Аннотация: A second generation phenylene dendrimer, viz. 1,3,5-tris[4-(3,5-diphenylphenyl)phenyl]benzene, was synthesized by cyclocondensation of 4-acetyl-3′,5′-diphenyl(biphenyl). This compound on heating to 600°C is transformed into substance possessing extremely heat-stable secondary structure. It retains the aromatic structure at this temperature and when heated to 1000°C is converted into material with graphite-like structure.

Ключевые слова: 4-acetyl-3′,5′-diphenyl(biphenyl), phenylene dendrimers, 1,3,5-tris[4-(3,5-diphenylphenyl)phenyl]benzene, thermal stability.

Язык публикации: английский

DOI: 10.1016/j.mencom.2021.04.038



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