Chemical looping methane dry reforming over Ni-containing modified ceria-zirconia

Modified ceria-zirconia oxides were prepared in supercritical fluids in flow-type installation. Ni was added by wetness impregnation. All materials were studied by a complex of physicochemical techniques (XRD, TEM, H$_2$-TPR). Catalysts have been investigated in a modern process – chemical looping methane dry reforming (CLMDR). Conversions of CH$_4$ and CO$_2$, H$_2$/CO ratio, H$_2$ and CO productivities were calculated. The features of CLMDR process were compared with results obtained in MDR steady-state conditions.